RESEARCH
PUBLICATIONS
PhD & DSc THESES
PATENTS


 

List of publications

2018

Pavlov D., Naidenov V., Milusheva Y., Vassilev S., Shibahara T., Tozuka M, Benzyl benzoate as an inhibitor of the sulfation of negative electrodes in lead-acid batteries, Journal of Energy Storage 17 (2018) 336-344, ISSN 2352-152X

 

I. Derafa, Zerroual, M. Matrakova., On the electrochemical activity of β-lead dioxide in sulfuric acid solution: a comparative study between the chemical and electrochemical routes. Journal of Solid State Electrochemistry, 22:4 (2018) 1175-1183, ISSN:1433-0768

2017

Detchko Pavlov, Lead-Acid Batteries: Science and Technology, Second Edition, 720 pages, Published by Elsevier B. V., Amsterdam, The Netherlands, 2017, ISBN 978-0-444-59552-2

 

A. Rusin, V. Naidenov, A. Kudriavtsev, Modern Lead-Acid Batteries,, Edited by A. Rusin, Saint-Petersburg, 2017 (Translated version a book published in Russian, Petropolis Publishing House, Saint-Petersburg, Russia, 2016, ISBN: 978-5-9676-0812-4)

 

P. Atanassova, A. Du Pasquier, M. Oljaca, P. Nikolov, M. Matrakova, D. Pavlov, Carbon additives in advanced lead-acid batteries: solutions and opportunities, Proc. 10th Intl. Conference on Lead-Acid Batteries, 13-16 June 2017, Golden Sands, Bulgaria, pp. 9-12, ISSN: 2367-4881

 

M. Mladenov, L. Stoyanov, S. Vassilev, L. Soserov, Effect of the electrodes and cell structures on the properties of the PbO2//C-Pb quasi-asymmetric supercapacitor, Proc. 10th Intl. Conference on Lead-Acid Batteries, 13-16 June 2017, Golden Sands, Bulgaria, pp. 61-64, ISSN: 2367-4881

 

D. Pavlov, , Elementary processes taking place during charge and discharge of lead-acid batteries, Proc. 10th Intl. Conference on Lead-Acid Batteries, 13-16 June 2017, Golden Sands, Bulgaria, pp. 75-78, ISSN: 2367-4881

 

I. Derafa, M. Matrakova, L. Zerroual, On the electrochemical activity of beta-lead dioxide in sulfuric acid solution: a comparative study between the chemical and electrochemical routes, Proc. 10th Intl. Conference on Lead-Acid Batteries, 13-16 June 2017, Golden Sands, Bulgaria, pp. 143-146, ISSN: 2367-4881

 

B. Shirov, V. Naidenov, Novel technology for production of lead-acid batteries by application of low energy impact technology (LEIT), Proc. 10th Intl. Conference on Lead-Acid Batteries, 13-16 June 2017, Golden Sands, Bulgaria, pp. 155-160, ISSN: 2367-4881

 

O. Saoudi, M. Matrakova, A. Aleksandrova, L. Zerroual, On the electrochemical behaviour of Pb-Sb-Se alloy in sulfuric acid solution: effect of surfactants, Proc. 10th Intl. Conference on Lead-Acid Batteries, 13-16 June 2017, Golden Sands, Bulgaria, pp. 255-258, ISSN: 2367-4881

2016

А. Русин, В. Найденов, А. Кудрявцев, Современные свинцовые аккумуляторы, Санкт-Петербург, ООО Издательский дом „Петрополис”, Санкт Петербург, Россия, 2016, ISBN:978-5-9676-0812-4

 

N. Chahmana, M. Matrakova, L. Zerroual,Physicochemical and electrochemical study of lead acid battery positive active mass (PAM) modified by the addition of bismuth, Bulgarian Chemical Communications, 48 : 2, (2016) 285-289, ISSN: 0324-1130

 

B. Naughton, S. Ruevski, D. Pavlov,How a composite scrim laminate can reduce degradation of PAM and so extend EFB cycle life, Batteries International, 98, Mustard Seed Publishing, 2016, ISSN:0957-9249, pp. 22-26

 

B. Naughton, S. Ruevski, D. Pavlov, Pode um único material melhorar em 40% a vida ciclada das baterias? | Can a single material improve by 40% the cycle life of batteries?, Pb Brazil – S. America, (Revista PbBrazil) 5, 17, 2016, pp. 54-61

2015

B. Drenchev, M. Dimitrov, V. Boev, A. Aleksandrova, Absorptive glass mat separator surface modification and its influence on the heat generation in valve-regulated lead-acid battery.,J. Power Sources 280 (2015) 66-73

 

M. Foudia, L. Zerroual, M. Matrakova, Effect of mineral additive on the electrical performance of lead-acid battery positive plate,J. Power Sources 279 (2015) 146-150

2014

P. Atanassova, A. Du Pasquier, M. Oljaca, P. Nikolov, M. Matrakova, D. Pavlov, Carbon additives for deep cycling lead-acid battery applications, Proc. 9th Intl. Conference on Lead-Acid Batteries,10-13 June 2014, Albena, Bulgaria, pp. 5-8, ISSN: 2367-4881

 

P. Nikolov, M. Matrakova, D. Pavlov, P. Atanassova, A. Du Pasquier, M. Oljaca, Carbon additives for improving charge acceptance of flooded lead-acid batteries,Proc. 9th Intl. Conference on Lead-Acid Batteries, 10-13 June 2014, Albena, Bulgaria, pp. 9-12, ISSN: 2367-4881

 

M. Foudia, M. Matrakova, L. Zerroual, Effect of mineral additive on the electrical performance of lead acid battery positive plate,Proc. 9th Intl. Conference on Lead-Acid Batteries,10-13 June 2014, Albena, Bulgaria, pp. 93-96, ISSN: 2367-4881

 

N. Chahmana, M. Matrakova, L. Zerroual, Physicochemical and electrochemical study of positive active mass (PAM) modified by the addition of Bismuth,Proc. 9th Intl. Conference on Lead-Acid Batteries,10-13 June 2014, Albena, Bulgaria, pp. 97-100, ISSN: 2367-4881

 

M. Matrakova, V. Naidenov, "State of Health" of electrodes of starter lead-acid batteries operated at low temperatures,Proc. 9th Intl. Conference on Lead-Acid Batteries,10-13 June 2014, Albena, Bulgaria, pp. 125-128, ISSN: 2367-4881

2013

D. Pavlov, P. Nikolov, Capacitive carbon and electrochemical lead electrode systems at the negative plates of lead-acid batteries and elementary processes on cycling, J. Power Sources 242 (2013) 380

2012

D. Pavlov and P. Nikolov, Lead–Carbon Electrode with Inhibitor of Sulfation for Lead-Acid Batteries Operating in the HRPSoC Duty, J. Electrochem. Soc., 159:8 (2012) A1215-A1225.

 

V. Naidenov, U. Markov, Influence of ultrasonic waves on the formation of lead-acid batteries, J. Power Sources217 (2012) 236

 

D. Pavlov, P. Nikolov, Lead-carbon electrode with inhibitor of PbSO4 recristalization in lead-acid batteries operating on HRPSoC duty, ECS Transactions, Volume 41 Is. 13 (2012) 71

 

M. Foudia, M. Matrakova, L. Zerroual, PbSO4 as a precursor for positive active material electrodes, J. Power Sources, 207 (2012) 51

2011

D. Pavlov, P. Nikolov, Lead-carbon electrode with inhibitor of PbSO4 recristalization in lead-acid batteries operating on HRPSoC duty, Meeting Abstracts of 220th ECS Meeting & Electrochemical Energy Summit, October 9-14, Boston, MA, Section B8, Abstract #710

 

P. Atanassova, P. Kossyrev, G. Moeser, M. Oljaca, P. Nikolov, T. Rogachev, D. Pavlov, Novel Carbon Materials for Improved Cycleability and Dynamic Charge Acceptance in Advanced Lead–Acid Battery Applications, Proceedings of the 14thAsian Battery Conference, 13-16 September 2011, Hyderabat, India

 

D. Pavlov, Lead-Acid Batteries: Science and Technology, 656 Pages
ISBN 10: 0-444-52882-2, ISBN 13: 978-0-444-52882-7, Elsevier B.V., Amsterdam, The Netherlands, 2011

 

D. Pavlov, P. Nikolov, T. Rogachev, Influence of carbons on the structure of the negative active material of lead-acid batteries and on battery performance, J. Power Sources 196:11 (2011) 5155

 

P. Nikolov, T. Rogachev, P. Atanassova, D. Pavlov, Addition of carbon blacks with different structure to the negative active mass for improving the HRPSoC performance of lead-acid batteries, Proceedings of the 8th International conference LABAT’2011, 7-10 June 2011,Albena, Bulgaria, p.9

 

D. Pavlov, P. Nikolov, T. Rogachev, Lead-Carbon electrode in lead-acid batteries operating at HRPSoC duty, Proceedings of the 8th International conference LABAT’2011, 7-10 June 2011, Albena, Bulgaria, p.13

 

M. Foudia, M. Matrakova, L. Zerroual, PbSO4 as a precursor for PAM electrodes, Proceedings of the 8th International Conference LABAT’2011, 7-10 June 2011, Albena, Bulgaria, p.77

2010

D. Pavlov, P. Nikolov and T. Rogachev, Influence of expander components on the processes at the negative plates of lead-acid cells on HRPSoC cycling. Part I. Effect of lignosulfonates and BaSO4 on the processes of charge and discharge of negative plates, J. Power Sources, 195 (2010) 4435

 

D. Pavlov, P. Nikolov and T. Rogachev , Influence of expander components on the processes at the negative plates of lead-acid cells on HRPSoC cycling. Part II. Effect of carbon additives on the processes of charge and discharge of negative plates. Nanotechnological effects, J. Power Sources, 195 (2010) 4444

 

D. Pavlov, P. Nikolov, T. Rogachev, Influence of expander components on the reversibility of the charge-discharge processes in lead-acid batteries for electric vehicle applications, Proceedings of the 12th European Lead Battery Conference, Istanbul, Turkey, 21–24 September 2010

 

M. Dimitrov, B. Drenchev, D. Valkovska and D. Pavlov, Mechanism of Thermal Phenomena in Valve-Regulated Lead-Acid Batteries with Operating Closed Oxygen Cycle, Proceedings of the 12th European Lead Battery Conference, Istanbul, Turkey, 21–24 September 2010

 

M. Dimitrov, B. Drenchev, D. Pavlov, Y. Ding, S. Zanardelli, Thermal phenomena in valve-regulated batteries with operating closed oxygen cycle, Proceedings of the 44th Power Sources Symposium, Las Vegas, USA, 14-17 June 2010, p.83

 

D.Pavlov, P. Nikolov, T. Rogachev, Influence of expander components on cycle life of lead-acid batteries for hybrid electrical vehicle applications, Proceeding of IBRX INDIA-2010, 3-5 March 2010, Hyderabat, India

2009

D. Pavlov, Electrolyte, In: Encyclopedia of Electrochemical Power Sources, Vol. 4, Amsterdam (Editor in chief  J. Garche), Elsevier B.V., Amsterdam, The Netherlands, 2009, pp. 610-619

 

G. Papazov, Negative Electrode, In: Encyclopedia of Electrochemical Power Sources (Editor in chief  J. Garche), Vol. 4, Elsevier B.V., Amsterdam, The Netherlands, 2009, pp. 579-589

 

V. Naidenov, D. Pavlov, M. Cherneva, Three-layered absorptive glass mat separator with membrane,  J. Power Sources, 192 (2009) 730

 

D. Valkovska, M. Dimitrov, T. Todorov, D. Pavlov, Thermal behavior of VRLA battery during closed oxygen cycle operation, J. Power Sources, 191 (2009) 119

 

M. Foudia, L. Zerroual, M. Matrakova, Plates soaking prior formation and its influence on positive active material phase composition and battery performance, J. Power Sources, 191 (2009) 76

 

D. Pavlov, T. Rogachev, P. Nikolov, G. Petkova, Mechanism of action of electrochemically active carbons on the processes that take place at the negative plates of lead-acid batteries, J. Power Sources, 191 (2009) 58

 

N. Chahmana, M. Matrakova, L. Zerroual, D. Pavlov,  Influence of some metal ions on the structure and properties of doped β-PbO2, J. Power Sources, 191 (2009) 51

 

N. Chahmana, L. Zerrouala, M. Matrakova, Influence of Mg2+, Al3+, Co2+, Sn2+ and Sb3+ on the electrical performance of doped b-lead dioxide, J. Power Sources 191 (2009) 144

2008

D. Pavlov, T. Rogachev, P. Nikolov, G. Petkova, Mechanism of active carbons on the processes that take place at the negative plates of lead-acid batteries, Proceedings of the 11th European Lead Battery Conference, Warsaw, Poland, 23–26 September 2008

 

P. Nikolov, G. Petkova, T. Rogachev, D. Pavlov, Negative plate additives for improving HRPSoC operation of lead-acid batteries, Proceedings of the 7th International conference LABAT’2008, 9-12 June 2008, Varna, Bulgaria, p. 5

 

G. Papazov, D. Pavlov, Influence of H2SO4/(Pb3O4 + leady oxide) ratio on the phase composition, structure and performance parameters of lead-acid battery positive plates, Proceedings of the 7th International conference LABAT’2008, 9-12 June 2008, Varna, Bulgaria, p. 73

 

M. Foudia, L. Zerroual, M. Matrakova, Plates soaking prior formation and its influence on PAM phase composition and battery performance, Proceedings of the 7th International conference LABAT’2008, 9-12 June 2008, Varna, Bulgaria, p. 65

 

D. Valkovska, T. Todorov, M. Dimitrov, D. Pavlov, Thermal behaviour of small battery during closed oxygen cycle, Proceedings of the 7th International conference LABAT’2008, 9-12 June 2008, Varna, Bulgaria, p. 147

 

M. Matrakova, D. Pavlov, N. Chahmana, L. Zerroual, Influence of Mg, Al, Co, Sn and Sb on the structure of doped βPbO2, Proceedings of the 7th Inter-national conference LABAT’2008, 9-12 June 2008, Varna, Bulgaria, p. 165

 

N. Chahmana, L. Zerroual, M. Matrakova, Influence of Mg, Al, Co, Sn and Sb on the electrical performance of doped βPbO2, Proceedings of the 7th Inter-national conference LABAT’2008, 9-12 June 2008, Varna, Bulgaria, p. 171

 

D. Pavlov, G. Petkova, T. Rogachev, Influence of H2SO4 concentration on the performance of lead-acid battery negative plates, J. Power Sources175 (2008) 586

2007

V.B. Naidenov, Tungsten carbide for gas-recombination electrodes – Review, Bulg. Chem. Comm., 39:3 (2007) 237

2006

D. Pavlov, “Essentials of Lead-Acid Batteries”, compiled and edited by B. Hariprakash, T. Prem Kumar, A.K. Shukla, published by SAEST, Karaikudi, India, 2006

 

E. Lamaire-Potteau, X. Vallve, D. Pavlov, G. Papazov, N.V. der Borg, J.F. Sarrau, ABLE project: Development of an advanced lead-acid storage system for autonomous PV installations, J. Power Sources162 (2006) 884

 

A. Kirchev, D. Pavlov, Influence of temperature and electrolyte saturation on rate and efficiency of oxygen cycle in VRLAB, J. Power Sources162 (2006) 864

 

D. Pavlov, V. Naidenov, S. Ruevski.  Influence of H2SO4 concentration on lead-acid performance. H-type and P-type batteries, J. Power Sources, 161 (2006) 658

 

A. Gigova, Investigation of the porous structure of battery separators using various porometric methods, J. Power Sources, 161 (2006) 1054

 

M. Matrakova, D. Pavlov, Thermal analysis of lead-acid battery pastes and active materials, J. Power Sources158 (2006) 1004

 

D. Pavlov,  Thermal phenomena during operation of the oxygen cycle in VRLAB and processes that cause them, J. Power Sources158 (2006) 964

 

G. Petkova, P. Nikolov, D. Pavlov, Influence of polymer additives on the performance of lead-acid battery negative plates, J. Power Sources158 (2006) 841

 

D. Pavlov, B. Monahov, A. Kirchev, D. Valkovska, Thermal runaway in VRLAB – Phenomena, reaction mechanisms and monitoring, J. Power Sources158 (2006) 689

 

J. Morales, G. Petkova, M. Cruz and A. Caballero, Synthesis and characterization of lead dioxide active material for lead-acid batteries, J. Power Sources, 158 (2006) 831

2005

G. Petkova, P. Nikolov, D. Pavlov,Influence of polymer additives on the per-formance of lead-acid battery negative plate, Proceedings of the 6th Inter-national conference LABAT’2005, 13-16 June 2005, Varna, Bulgaria, p. 171

 

M. Matrakova, D. Pavlov,Thermal analysis of lead-acid battery pastes and active materials, Proceedings of the 6th International conference LABAT’2005, 13-16 June 2005, Varna, Bulgaria, p. 129

 

E.Lemaire-Potteau, D.Pavlov, G.Papazov, X.Vallve, N. Van der Borg, J.F.Sarrau, ABLE project: advanced lead-acid battery with optimized mana-gement system for the photovoltaic application, Proceedings of the 6th Inter-national conference LABAT’2005, 13-16 June 2005, Varna, Bulgaria, p. 43

 

A. Kirchev, D. Pavlov, A. Gigova, Effect of electrolyte saturation on rate and efficiency of oxygen cycle in VRLAB, Proceedings of the 6th International conference LABAT’2005, 13-16 June 2005, Varna, Bulgaria, p. 25

 

D. Valkovska,  D. Pavlov, A. Kirchev, Heat generation in VRLA battery – influence of separator type (poster), Proceedings of the 6th International conference LABAT’2005, 13-16 June 2005, Varna, Bulgaria, p. 19

 

D. Pavlov, B. Monahov, A. Kirchev, D. Valkovska, Thermal phenomena in VRLAB, Proceedings of the 6th International conference LABAT’2005, 13-16 June 2005, Varna, Bulgaria, p. 5

 

D. Pavlov, A. Kirchev, B. Monahov, Mechanism of the oxygen cycle reactions proceeding at the negative plates of VRLAB, J. Power Sources, 144 (2005) 521

 

M. Dimitrov, D. Pavlov, T. Rogachev, M. Matrakova, L. Bogdanova, Processes taking place in the paste of lead-acid battery plates during soaking prior to formation and their influence on the battery performance, J. Power Sources, 140 (2005) 168.

 

P. Nikolov, G. Petkova, D. Pavlov, Influence of fluoropolymers on the performance of lead-acid battery negative plates, Proceeding of International Workshop “Portable and emergency energy sources – from materials to systems”, 16 – 22 September, 2005, Primorsko, Bulgaria.

 

J. Morales, G. Petkova, M. Cruz and A. Caballero, Nanostructured PbO2  an active material with high efficiency for lead-acid batteries, Proceedings of the 6th International conference LABAT’2005, 13-16 June 2005, Varna, Bulgaria, p.233

 

J. Morales, G. Petkova, M. Cruz and A. Caballero, Synthesis and characterization of lead dioxide active material for lead-acid batteries, Proceedings of International conference LABAT-05, 13-16 June, 2005, Varna, Bulgaria, p.229

2004

D. Pavlov, A. Kirchev, M. Stoycheva, B. Monahov , Influence of H2SO4 concentration on the mechanism of the processes and on the electrochemical activity of the Pb/PbO2/PbSO4 electrode, J. Power Sources, 137 (2004) 288

 

D. Pavlov, Problems, research and development into VRLA batteries, Batteries International, Is. 60, (2004) p. 49

 

D. Pavlov, Chapter 3, Formation of Lead-Acid Batteries and Structure of Positive and Negative Active Masses, Valve Regulated Lead Acid Batteries (Eds. D.A.J. Rand, P.T. Moseley, J. Garche, C.D. Parker) p. 37-108,  Elsevier, Amsterdam, 2004

 

J. Morales, G. Petkova, M. Cruz and A. Caballero, Nanostructured Lead Dioxide Thin Electrode, Electrochemical and Solid-State Letters, 7: 4  (2004) A75-A77

 

2. J. Morales, G. Petkova, M. Cruz and A. Caballero, Synthesis, characterization and electrochemical properties of nanostructured lead dioxide, Nanoscience & Nanotechnology (eds. E. Balabanova, I. Dragieva) v.4, p.243., Heron Press, Sofia, 2004,

2003

D. Pavlov, S. Ruevski, V. Naidenov, V. Mircheva, G. Petkova, M. Dimitrov, T. Rogachev, M. Cherneva-Vasileva, Valve-regulated lead-acid cells and batteries and separators used in such cells and batteries. U.S.Patent Nо:  6509118 B1, Date of Patent: Jan. 21, 2003

 

D. Pavlov, M. Dimitrov, T. Rogachev, L. Bogdanova, Influence of paste composition and curing program used for the production of positive plates with PbSnCa grids on the performance of lead acid batteries, J. Power Sources, 114 (2003) 137.

 

G. Petkova and D. Pavlov, Influence of charge mode on the capacity and cycle life of lead–acid battery negative plates, J. Power Sources, 113 (2003) 355.

 

M. Matrakova, T. Rogachev, D. Pavlov and B. O. Myrvold, Influence of phenolic group content in lignin expanders on the performance of negative lead–acid battery plates, J. Power Sources, 113 (2003) 345.

 

G. Papazov, D. Pavlov, and B. Monahov, Influence of temperature on expander stability and on the cycle life of negative plates, J. Power Sources, 113 (2003) 335.

 

B. Monahov, D. Pavlov, A. Kirchev and S. Vasilev, Influence of pH of the H2SO4 solution on the phase composition of the PbO2 active mass and of the PbO2 anodic layer formed during cycling of lead electrodes, J. Power Sources, 113 (2003) 281.

 

D. Pavlov, G. Papazov and B. Monahov, Strap grid tubular plate – a new positive plate for lead–acid batteries. Processes of residual sulphation of the positive plate, J. Power Sources, 113 (2003) 255.

 

A. Kirchev, D. Pavlov and B. Monahov, Gas-diffusion approach to the kinetics of oxygen recombination in lead-acid batteries, J. Power Sources, 113 (2003) 245.

 

D. Pavlov, V. Naidenov, S. Ruevski, V. Mircheva and M. Cherneva, New modified AGM separator and its influence on the performance of VRLA batteries, J. Power Sources, 113 (2003) 209.

 

T. J. McNally, M. Е. Sanford, B. О. Myrvold, D. Pavlov, T. Rogachev, G. Rapazov, M. Matrakova, Organic expander for lead-acid storage batteries, U.S.Patent Nо:  6664002 B2, Date of Patent: Dec. 16, 2003

2002

A. Kirchev, B. Monahov, D. Pavlov, Gas-diffusion approach to the kinetics of oxygen recombination in lead-acid batteries, Proceedings of International Conference LABAT’02, Varna, 10-13 June 2002, p.131

 

G. Petkova, D. Pavlov, Influence of charge mode on the capacity and cycle life of lead-acid battery negative plates, Proceedings of International Conference LABAT’02, Varna, 10-13 June 2002, p. 119

 

M. Matrakova, T. Rogachev, D. Pavlov, B.O. Myrvold, Influence of phenolic group content in lignin expanders on the performance of negative lead-acid battery plates, Proceedings of International Conference LABAT’02, Varna, 10-13 June 2002, p.113

 

G. Papazov, D. Pavlov, B. Monahov, Influence of temperature on expander stability and on the cycle life of the negative plates, Proceedings of International Conference LABAT’02, Varna, 10-13 June 2002, p.105

 

D. Pavlov, M. Dimitrov, T. Rogachev. L. Bogdanova,Influence of the curing conditions on PbCaSn grid/paste interface and lead-acid battery performance, Proceedings of International Conference LABAT’02, Varna, 10-13 June 2002, p.79

 

B. Monahov, A. Kirchev, A. Vasilev, D. Pavlov,Influence of pH on the structure and phase composition of PbO2 anodic layers formed on Pb electrodes in H2SO4 solution, Proceedings of International Conference LABAT’02, Varna, 10-13 June 2002, p.51

 

D. Pavlov, G. Papazov, B. Monahov, Strap Grid Tubular Plate – a new plate for lead-acid batteries, Proceedings of International Conference LABAT’02, Varna, 10-13 June 2002, p.39

 

D. Pavlov, V. Naidenov, S. Ruevski, V. Mircheva, M. Cherneva, New modified AGM separator and its influence on the performance of VRLAB, Proceedings of International Conference LABAT’02, Varna, 10-13 June 2002, p.5

 

T. J. McNally, M. Е. Sanford, B. О. Myrvold, D. Pavlov, T. Rogachev, G. Rapazov, M. Matrakova, Organic expander for lead-acid storage batteries, U.S.Patent Nо:  6346347 B1, Date of Patent: Feb. 12, 2002

 

D. Pavlov, G. Petkova, Phenomena that limit the capacity of the positive lead acid battery plates. 2. Electrochemical impedance spectroscopy and mechanism of discharge of the plate. J. Electrochem. Soc., 149  (2002) A654.

 

D. Pavlov, G. Petkova, Phenomena that limit the capacity of the positive lead acid battery plates. 1. The charge potential transient as an indicator of positive plate state of charge and state of health. J. Electrochem. Soc., 149 (2002) A644.

2001

M. Dimitrov, D. Pavlov, Influence of grid alloy and fast charge on battery cycle life and structure of the positive active mass of lead acid batteries, J. Power Sources, 93 (2001) 234.

 

D. Pavlov, S. Ruevski, Semi-suspensoin technology for preparation of tetrabasic lead sulfate pastes for lead-acid batteries. J. Power Sources, 95 (2001) 191.

2000

D. Pavlov, S. Ruevski, V. Naidenov, G. Sheytanov, Influence of temperature, current and number of cycles on the efficiency of the closed oxygen cycle in VRLA batteries, J. Power Sources, 85 (2000) 164.

 

D. Pavlov, S. Ruevski, A method to control the skeleton and energetic structure of positive active material aimed at improving the capacity and cycle life of lead-acid batteries. Proceedings of 7th European lead battery conference, Dublin, 19-22 September 2000 p. 5.3.

 

D. Pavlov, G. Petkova, M. Dimitrov, M. Shiomi, M. Tsubota, Influence of fast charge on the cycle life of positive lead-acid batteries plates, J. Power Sources, 87 (2000) 39.

 

D. Pavlov, Development of lead-acid battery in the first decade of the new millennium, Chinese J. Power Sources, 25 (2001) 2, key lecture in ILBF China 2000

 

D. Pavlov, Development of lead-acid battery in the first decade of the new millennium, Chinese J. Power Sources, 25 (2001) 107, key lecture in ILBF China 2000

 

D. Pavlov, Development in the near future, key lecture, 51st Annual ISE Meeting, Warsaw, 2000.

 

D. Pavlov, B.O. Myrvold, T. Rogachev, M. Matrakova, A new generation of highly efficient expander products and correlation between their chemical composition and the performance of the lead-acid battery, J. Power Sources, 85 (2000) 79.

 

D. Pavlov, B. Monahov, Influence of Ag as alloy additive on the oxygen evolution reaction on Pb/PbO2electrode, J. Power Sources, 85 (2000) 59.

 

B.O. Myrvold, D. Pavlov, Multivariate analysis for characterization of expanders, J. Power Sources, 85 (2000) 92.

1999

D. Pavlov, S. Ruevski, P. Eirich, A. Burschka, Influence of the method of 4PbO.PbSO4 preparation on the performance of the lead-acid batteries, Proceedings of International conference LABAT’99, Sofia, 7-10 June, 1999, p.137.

 

M. Dimitrov, D. Pavlov, M. Shiomi, M. Tsubota, Influence of fast charge on the structure and properties of lead-dioxide active mass, Proceedings of International conference LABAT’99, Sofia, 7-10 June 1999, p.75.

 

G. Papazov, B. Monahov, D. Pavlov, Influence of PAM density on the cycle life of positive lead-acid battery plates, Proceedings of International conference LABAT’99, Sofia, 7-10 June 1999, p.65.

 

B. Myrvold, D. Pavlov, T. Rogachev, M. Matrakova, G. Rodsrud, A new generation of highly efficient expander products and correlation between their chemical composition and the performance of the lead-acid battery, Proceedings of International conference LABAT’99, Sofia, 7-10 June, 1999, p.37.

 

B. Myrvold, D. Pavlov, Multivariate analysis for characterization of expanders, Proceedings of International conference LABAT’99, Sofia, 7-10 June, 1999, p.33.

 

B. Monahov, D. Pavlov, D. Petrov, Influence of Ag on the oxygen evolution reaction on Pb/PbO2 electrode, Proceedings of International conference LABAT’99, Sofia, 7-10 June, 1999, p.85.

 

B. Monahov, D. Pavlov, D. Petrov, Influence of alloying additives (Sb, Sn, Ca, Ag) on the oxygen evolution reaction on Pb/PbO2 electrodes, Proceedings of 15th Annual Battery Conference on Applications and Advances, Long Beach, 12-15 Jan., 1999, p.275.

1998

D. Pavlov, St. Ruevski, P. Eirich, A. C. Burschka, A New Technology For Preparation of Pastes For Lead-Acid Batteries, The Battery Man, April 1998, p.16.

 

D. Pavlov, S. Ruevski, P. Eirich, A. Burschka, Influence of the method of 4PbO.PbSO4 preparation on the performance of the lead-acid batteries, Proceedings of 6th European lead battery conference, Prague, 21-25 September 1998 p.1.4.

 

D. Pavlov, B. Monahov, Temperature Dependence of the Oxygen Evolution Reaction on the Pb/PbO2 Electrode, J. Electrochem. Soc., 145 (1998) 70.

 

D. Pavlov, B. Monahov, Influence of alloying additives (Sb, Ca, Sn, Ag) on the oxygen evolution reaction on Pb/PbO2 electrode, Proceedings of 6th European Lead Battery Conference, Prague, 21-25 September 1998 p. 3.2.

1997

T. Rogachev, D. Pavlov, Influence of cycling on the nature of the positive active mass of lead-acid batteries and effect of CaSO4 on the behaviour of the positive plates, J. Power Sources, 64, 51 (1997).

 

D. Pavlov, Energy balance of the closed oxygen cycle and processes causing thermal runaway in valve regulated lead-acid batteries, J. Power Sources, 64 (1997) 131.

 

D. Pavlov, B. Monahov, Temperature Dependance of the Oxygen Evolution Reaction on the Pb/PbO2 Electrode. I. PbO2 Layer Formed Through Oxidation of the Pb Electrode, “Batteries for Portable Application and Electric Vehicles”, Ed., C. F. Holmes, A. R. Landgrebe, Proceedings, vol 18 (1997) The Electrochemical Society, Inc., Pennington, NJ, p. 669-692.

 

D. Pavlov, A. Dakhouche, T. Rogachev, Influence of antimony ions and PbSO4 content in the corrosion layer on the properties of the interface grid/active mass in positive lead-acid battery plates, J. Applied Electrochem., 27 (1997) 720.

 

D. Pavlov, Some problems in Valve Regulated Lead-Acid Batteries and how to solve them, Electrical Power Sources Yugoslavia, 85 (1997) 11

1996

T. Rogachev, D. Pavlov, Influence of CaSO4 on the properties of the positive lead-acid battery plates, Proceedings of extended Abstracts, LABAT’96 International conference, p. 29, Varna, June 1996.

 

S. Ruevski, D. Pavlov, Influence of BaSO4 content in the negative SLI battery plates on their performance, Proceedings of extended Abstracts, LABAT’96 International conference, p.46, Varna, June 1996.

 

M. Bojinov, D. Pavlov, Electrical and electrochemical properties of PbO2 plate of lead-acid cell, Proceedings of extended Abstracts, LABAT’96 International conference, p.83, Varna, June 1996.

 

G. Papazov, D. Pavlov, Influence of cycling current and power profiles on the cycle life of lead-acid batteries, J. Power Sources, 62 (1996) 193.

 

G. Papazov, D. Pavlov, Influence of cycling current and power profiles on the cycle life of lead-acid batteries, Proceedings of extended Abstracts, LABAT’96 International conference, p.3, Varna, June 1996.

 

D. Pavlov, Processes causing thermal runaway in VRLA batteries, Proceedings of extended Abstracts, LABAT’96 International conference, p.133, Varna, June 1996.

 

D. Pavlov, B. Monahov, The temperature dependence of oxygen evolution on the lead dioxide electrode in sulphuric acid solution, Proceedings of extended Abstracts, LABAT’96 International conference, p.129, Varna, June 1996.

 

D. Pavlov, B. Monahov, Mechanism of the elementary electrochemical processes taking place during oxygen evolution on the lead dioxide electrode, J. Electrochem. Soc., 143 (1996) 3616.

1995

D. Pavlov, M. Dimitrov, G. Petkova, H. Giess, C. Gnehm, The effect of selenium on the electrochemical behaviour and corrosion of Pb-Sn alloys used in lead-acid batteries, J. Electrochem. Soc., 142  (1995) 2919.

 

D. Pavlov, A theory of the grid/positive active mass  (PAM) interface and possible methods to improve PAM utilization and cycle life of lead/acid batteries, J. Power Sources, 53 (1995) 9

1994

L.T. Lam, L.G. Mawston, D. Pavlov, D.A.J. Rand, Aspects of Lead/Acid Battery Manufacture and Performance, J. Power Sources 48 (1994) 257-268.

 

D. Pavlov, Effect of the corrosion layer on the phenomena causing premature capacity loss (PCL), J. Power Sources, 48 (1994) 179 - 193.

 

G. Papazov, I. Nikolov, D. Pavlov, T. Vitanov, Application of WC Electrodes in Stationary Batteries, Proceedings TELESCON'94 Conference, Berlin, 1994, p. 463.

 

D. Pavlov, M. Dimitrov, G. Petkova, H. Giess, C. Gnehm, Corrosion of strap and lugs of the negative plates in VRLA batteries, Extended Abstracts, Fall Meeting of the Electrochemical Society inc., Miami Beach, Florida, Vol. 84-2,p.254-255, Pennington NJ, USA, 1994.

 

M. Bojinov, D. Pavlov, The Antimony/Klebelsbergite Electrode, J.Electroanal. Chem., 367 (1994) 195

 

B. Monahov, D. Pavlov, Influence of Antimony on the Structure and Degree of Hydration of the Anodic PbO2 Layer Formed on Pb-Sb Electrodes, J. Electrochem. Soc., 141 (1994) 2316.

1993

S. Gancheva, D. Pavlov, Influence of Expander Structure on the Performance of Lead-Acid Battery Negative Plate, Proceedings of the International Conference LABAT'93, 7-11 June 1993, Varna, Bulgaria p. 156.

 

M.K. Dimitrov, D. Pavlov, Location of the phenomena of premature capacity loss during cycling of lead/acid batteries with lead grids, J. Power Sources, 46 (1993) 203 - 210.

 

M. Bojinov, D. Pavlov, Catalytic Effect of Bi on the Formation of Lead (IV) Oxides on Pb-Bi Alloys in H2SO4 Solutions, Proceedings of the International Conference LABAT'93, 7-11 June 1993, Varna, Bulgaria p. 72

 

M. Bojinov, D. Pavlov, Anodic Oxidation of Antimony at High Anodic Overpotential - Formation of a Barrier Layer and Klebelsbergite, J.Electroanal. Chem., 346 (1993) 339.

 

D. Pavlov, Suppression of premature capacity loss by methods based on the gel-crystal concept of the PbO2 electrode, J. Power Sources, 46 (1993) 171.

 

D. Pavlov, S. Ruevski, T. Rogachev, The Processes in the Positive Plates During Pickling Before Formation, Proceedings of the International Conference LABA '93, 7-11 June 1993, Varna, Bulgaria p. 152

 

D. Pavlov, S. Ruevski, T. Rogachev, Processes in positive lead/acid battery plates during soaking prior to formation, J. Power Sources, 46 (1993) 337-348.

 

D. Pavlov, S. Gancheva, P. Andreev, Effect of hydrogen and oxygen on stability of expanders and performance of lead/acid batteries, J. Power Sources, 46 (1993) 349-359.

 

D. Pavlov, Premature Capacity Loss (PCL) of the Positive Lead/Acid Battery Plate: Phenomena. New Concept., J. Power Sources, 42 (1993) 345.

 

D. Pavlov, Methods for Suppressing the Phenomena Causing Premature Capacity Loss (PCL) Based on the Gel-Crystal Concept of the PbO2Electrode, Proceedings of the International Conference LABAT'93, 7-11 June 1993, Varna, Bulgaria, p. 11.

 

D. Pavlov, A. Dakhouche, T. Rogachev, Influence of Antimony on the Electrochemical Behaviour and the Structure of the Lead Dioxide Active Mass of Lead-Acid Batteries, J. Power Sources, 42 (1993) 71.

 

B. Monahov, D. Pavlov, Influence of Antimony on the Amorphyzation of the Corrosion Layer, Proceedings of the International Conference LABAT '93, 7-11 June 1993, Varna, Bulgaria p. 61

 

G. Papazov, Energy consumption at lead-acid battery plates formation, Proceedings of the International Conference LABAT '93, 7-11 June 1993, Varna, Bulgaria  p.144

 

B. Monahov, D. Pavlov, Hydrated structures in the anodic layer formed on lead electrodes in H2SO4 solution, J. Applied Electrochem., 23 (1993) 1244.

1992

D. Pavlov, The Lead-Acid Battery Lead Dioxide Active Mass - a Gel-Crystal System with Proton and Electron Conductivity, J. Electrochem. Soc., 139 (1992) 3075.

 

D. Pavlov, Influence of Crystal and Gel Zones on the Capacity of the Lead Dioxide Active Mass of Lead-Acid Battery, J. Power Sources, 40 (1992) 169.

 

I. Nikolov, G Papazov, V. Najdenov, Performance of WC recombination electrodes under various operating conditions, J.Power Sources, 40 (1992) 341.

 

I. Nikolov, G. Papazov, V Najdenov, Activity and corrosion of WC recombination electrodes during lead-acid battery operation, J.Power Sources, 40 (1992) 333.

 

D. Pavlov, I. Balkanov, The PbO2 Particle: Exchange Reactions Between Ions of the Electrolyte and the PbO2 Particles of the Lead-Acid Battery Positive Active Mass, J. Electrochem. Soc., 139 (1992) 1830.

1991

T. Laitinen, K. Salmi, G. Sundholm, B. Monahov, D. Pavlov, The Effect of Antimony on the Anodic Behaviour of Lead in Sulphuric Acid Solution. 1. The Behaviour of Lead-Antimony Alloys During the Early Stage of Oxidation, Electrochim. Acta, 36 (1991) 605-614.

 

T. Laitinen, H. Revitzer, G. Sundholm, J. Vilhunen, D. Pavlov, M. Bojinov, Electrochemical Behaviour of the Antimony Electrode in H2SO4 Solutions. III. Identification of Corrosion Products after Long-Term Polarization, Electrochim. Acta, 36 (1991) 2093.

 

M. Bojinov, D. Pavlov, The Processes of Formation of a Gel-Like Anodic Layer During Polarization of an Antimony Electrode in H2SO4 Solution, J. Electroanal. Chem., 315 (1991) 201.

 

D. Pavlov, V. Iliev, Problems of the Battery Industry in Bulgaria, Batteries International, October 1991, LDA, London.

 

D. Pavlov, M. Bojinov, T. Laitinen, G. Sundholm, Electrochemical Behaviour of the Antimony Electrode in H2SO4 Solutions. II. Formation and Properties of the Primary Anodic Layer, Electrochim. Acta, 36 (1991) 2087.

 

D. Pavlov, M. Bojinov, T. Laitinen, G. Sundholm, Electrochemical Behaviour of the Antimony Electrode in H2SO4 Solutions. I. Corrosion and Active Dissolution of Antimony, Electrochim. Acta, 36 (1991), 2081.

 

T. Laitinen, B. Monahov, K. Salmi, G. Sundholm, Electrochim. Acta, 36 (1991) 953.

 

D. Pavlov, G. Papazov, M. Gerganska, Battery Energy Storage Systems, Technical Report No. 7, 102 ñòð., UNESCO (ROSTE), Venice, Italy, 1991.

 

D. Pavlov, Effect of Dopants (Group V) on the Performance of the Positive Lead-Acid Battery Plate, J. Power Sources, 33 (1991) 221.

 

D. Pavlov, B. Monahov, G. Sundholm, T. Laitinen, The Effect of Antimony on the Anodic Behaviour of Lead in Sulphuric Acid Solution. 2. Phase Composition of the Anodic Layer in Dependence of the Oxidation Potential, J. Electroanalyt. Chem., 305 (1991) 57-72.

1990

G. Papazov, I. Nikolov, D. Pavlov, T. Vitanov, Lead-Acid Battery with WC Recombination Electrodes, Bulletin of Electrochemistry, 6 (1990) 255.

 

D. Pavlov, N. Kapkov, High-Temperature Curing of Lead Acid Battery Positive Plates, J. Electrochem. Soc., 137 (1990) 21.

 

D. Pavlov, N. Kapkov, Lead-Acid Battery Pastes Containing 4PbO.PbSO4 and Pb3O4, J. Electrochem. Soc., 137 (1990) 16.

 

D. Pavlov, E. Bashtavelova, A Study of the Oxidation of 4PbO.PbSO4 Crystals in Cured Pastes to PbO2 Agglomerates during Formation of Positive Plates for Lead/Acid Batteries, J. Power Sources, 31 (1990) 243.

 

M. Dimitrov, Oxygen Evolution on Lead Dioxide in H2SO4 Solution, J. Power Sources, 31(1990) 121

 

S. Ruevski, D. Pavlov, Accelerated Curing of Negative Plates for Lead/Acid Batteries, J. Power Sources, 31 (1990) 217.

 

D. Pavlov, N. Kapkov, Lead-Acid Battery Positive Plates Manufactured from 4PbO.PbSO4 Pastes Prepared from Leady Oxide and Red Lead, J. Power Sources, 31 (1990) 189.

 

G. Papazov, I. Nikolov, D. Pavlov, T. Vitanov, P. Andreev, M. Bojinov, Sealed Lead/Acid Battery with Auxiliary Tungsten Carbide Electrodes, J. Power Sources, 31 (1990) 79.

 

I. Nikolov, G. Papazov, D. Pavlov, T. Vitanov, V. Naidenov, Tungsten Carbide Electrodes for Gas Recombination in Lead/Acid Batteries, J. Power Sources, 31 (1990) 69.

 

D. Pavlov, A. Dakhouche, T. Rogachev, Influence of Arsenic, Antimony and Bismuth on the Properties of Lead/Acid Battery Positive Plates, J. Power Sources, 30 (1990) 117.

 

D. Pavlov, E. Bashtavelova, D. Simonsson, P. Ekdunge, Processes at the Micro-Level in the Oxidation of PbSO4 to PbO2 during Charging of Lead/Acid Battery Positive Plates, J. Power Sources, 30 (1990) 77.

 

M. Bojinov, B. Monahov, J. Power Sources, 30 (1990) 287

1989

D. Pavlov, PbO2 Particles of the Positive Active Mass - A Complex Open Electrochemical System, Extended Abstracts, The 30th Battery Symposium in Japan, Nagoya, 1989, p. 3.

 

D. Pavlov, I. Balkanov, T. Halachev, P. Rachev, Hydration and amorphization of active mass PbO2 particles and their influence on the electrical properties of the lead-acid battery positive plate, J. Electrochem. Soc., 136 (1989) 3189.

 

D. Pavlov, B. Monakhov, M. Maja, N. Penazzi, Sn-Free Effect at the Positive Lead Acid Battery Plates, Revue Roumaine de Chimie, 34 (1989) 551.

 

D. Pavlov, B. Monakhov, M. Maja, N. Penazzi, Mechanism of action of Sn on the passivation phenomena in the lead-acid battery positive plate (Sn-free effect), J. Electrochem. Soc., 136 (1989) 27

1988

D. Pavlov, Reply to Comments of R.J. Hill on "Effect of chemisorbed water on the electrical capacity of lead-acid battery positive plate", J. Power Sources, 22 (1988) 179.

 

T. Rogachev, J. Power Sources, 23 (1988) 331

1987

D. Pavlov, S. Ignatova, "Breathing" of the lead-acid battery negative plate during cycling, J. Appl. Electrochem., 17 (1987) 715.

 

D. Pavlov, Processes during Discharge of the Lead-Acid Battery PbO2 Active Mass, Proceedings 31st International Congress IUPAC-87, p. 162, Sofia, Bulgaria, 1987.

 

D. Pavlov, Problems of the lead-acid batteries for navigational aids, IALABATT-87, IALA Workshop on Batteries Drujba-87, p. 50, Publ. by International Association of Lighthouse Authorities, Paris, France, 1987.

 

D. Pavlov, I. Pashmakova, Influence of the size of PbSO4 crystals on their solubility and the significance of this process in the lead-acid battery, J. Appl. Electrochem., 17 (1987) 1075.

 

D. Pavlov, I. Balkanov, P. Rachev, Orthorhombic PbO formation during discharge of lead-acid batteries PbO2 active mass, J. Electrochem. Soc., 134 (1987) 2390.

 

D. Pavlov, E. Bashtavelova, V. Manev, A. Nasalevska, Effect of chemisorbed water on the electrical capacity of the lead-acid battery positive plate, J. Power Sources, 19 (1987) 15.

 

D. Pavlov, B. Monakhov, Effect of Sb on the electrochemical properties of Pb/PbSO4/H2SO4 and Pb/PbO/PbSO4/H2SO4 electrodes, J. Electroanal. Chem., 218 (1987) 135.

 

D. Pavlov, Discharge processes in lead-acid battery positive plates, Power Sources - 11, 15th Intl. Symposium, Brighton 1986, Ed. L.J. Pearce, Pergamon Press, p. 165, London, 1987.

1986

Д. Павлов, Ст. Руевски, В. Илиев, Г. Папазов, Сухозаредени акумулатори с удължен срок на съхранение, Служебна публикация, ЦЛЕХИТ, 1986 г. (намира се в сейфа на ЦЛЕХИТ).

 

D. Pavlov, T. Rogatchev, Mechanism of the action of Ag and As on the anodic corrosion of lead and oxygen evolution at the Pb/PbO2/H2O/O2/H2SO4 electrode system, Electrochim. Acta, 31 (1986) 241.

 

D. Pavlov, E. Bashtavelova, Structural properties of the PbO2 active mass determining its capacity and the "breathing" of the positive plate during cycling, J. Electrochem. Soc., 133 (1986) 241.

 

G. Papazov, Mass transport during lead-acid battery plate formation, J. Power Sources, 18 (1986) 337

1985

V. Iliev, D. Pavlov, The effect of the expander upon the two types of negative active mass structure in lead-acid batteries, J. Appl. Electrochem., 15 (1985) 39.

 

M. Dimitrov, K. Kochev, D. Pavlov, The effect of the thickness and stoichiometry of the PbO layer upon the photoelectric properties of the Pb/PbO/PbSO4/H2SO4 electrode, J. Electroanal. Chem., 183 (1985) 145.

1984

Д. Павлов, В. Илиев, Г. Папазов, Получение, фазовый состав и микроструктура аккумуляторных паст, Химические источники тока, Сборник научных трудов, стр. 18, Энергоатомиздат, Ленинградков отделение, 1984.

 

D. Pavlov, Power Sources for Electric Vehicles (B.D. McNicol, D.A.J. Rand, eds.), Chapter 5, 400 ñòð., Elsevier Sequoia, Amsterdam, 1984.

 

D. Pavlov, Mechanism of the Processes during anodic oxidation of a lead electrode in sulphuric acid solutions, Advances in Lead-Acid Batteries, Proceedings of the International Symposium, Vol. 84-14, p. 110, Electrochem. Soc. Inc., Pennington, USA, 1984.

 

D. Pavlov, E. Bashtavelova, V. Iliev, Structure of the lead-acid battery active masses, Advances in Lead-Acid Batteries, Proceedings of the International Symposium, Vol.84-14, p. 16, Electrochem. Soc. Inc., Pennington, USA, 1984.   

 

D. Pavlov, E. Bashtavelova, A model of the structure of the positive lead-acid battery active mass, J. Electrochem. Soc., 131, (1984) 1468.

1983

T. Rogachev, G. Papazov, D. Pavlov, The Effect of Current Density and Thickness of Active Mass Upon the Corrosion Rate of the Spines of Lead-Acid Battery Plates, J. Power Sources, 10 (1983) 291.

1982

Ст. Руевски, В. Илиев, Д. Павлов, Методи за намаление на поддръжката на оловните акумулаторни батерии, Химия и индустрия, 3 (1982) 124.

 

V. Iliev, D. Pavlov, Self-discharge and passivation phenomena in lead-acid batteries during storage, J. Electrochem. Soc., 129 (1982), 453. 

1981

D. Pavlov, V. Iliev, Structure of the active mass of the negative plate of lead-acid batteries, J. Power Sources, 7 (1981) 153.

 

D. Pavlov, Semiconductor mechanism of the processes during electrochemical oxidation of PbO to PbO2, J. Electroanal. Chem. 118 (1981) 167.

 

D. Pavlov, S. Zanova, B. Monachov, M. Maja, E. Angelini, Electrochemical oxidation of Pb alloys with Ag, Sn and Ca to PbO2, 32 Meeting of ISE, Extended Abstracts, vol. 1, p. 142, Dubrovnik, Jugoslavia, 1981.

 

D. Pavlov, E. Bashtavelova, V. Iliev, Processes during the discharge of the positive lead-acid battery plate, 32 Meeting of ISE, Extended Abstracts, Part I, p.146, Dubrovnik, Yugoslavia, 1981.

1980

G. Papazov, T. Rogachev, D. Pavlov, J. Garche, K. Wiesener, Influence of Lead Dioxide Active Mass on the Grid Corrosion Rate of the Positive Lead-Acid Battery Plates, J. Power Sources, 6 (1980) 15.

 

D. Pavlov, Z. Dinev, Mechanism of the electrochemical oxidation of lead to lead dioxide electrode in H2SO4 solution, J.Electrochem.Soc., 127 (1980) 855

 

D. Pavlov, S. Zanova, M. Maja, E. Angelini, Influence of Ag, Ca and Sn ions on the photoelectrochemical properties of the lead electrode, 31 Meeting of ISE, Extended Abstracts, Vol.2, p. 609, Venice, Italy, 1980.

 

D. Pavlov, G. Papazov, Zone processes at the formation of lead-acid battery positive plate, J. Electrochem. Soc., 127 (1980) 2104.

1979

V. Iliev, D. Pavlov, Influence of PbO modification on the kinetics of the 4PbO.PbSO4 lead acid battery paste formation, J. Appl. Electrochem., 9 (1979) 555.

 

T. Rogachev, G. Papazov, D. Pavlov, Influence of Operating Conditions of Tubular Batteries on the Corrosion Rate of the Spine of Lead Dioxide Plates, Progress in Batteries and Solar Cells, 2 (1979) 145.

 

D. Pavlov, St. Ruevski, Thermopassivation of the lead dioxide plate of lead-acid batteries, J. Electrochem. Soc., 126 (1979) 1100.

 

1. G. Papazov, J.P. Pohl, H. Rickert, Cathodic pulse measurements with thin PbO2 layers, Power Sources, Ed. J. Thompson, p.37, Academic Press, L. 1979

1978

Д. Павлов, В. Илиев, Т. Рогачев, Ил. Металков, Г. Папазов, Ст. Руевски, С. Колев, И. Костадинов, Новое в конструкции и технологии изготовления стартерных свинцовых батерей, Сборник работ по химическим источникам тока, Энергия, Ленинград,12 (1978) 24.

 

G. Papazov, D. Pavlov, Abhangigkeit der Formierungs-prozesse der positiven Platte des Bleiakkumulators von der Formierungs-stromdichte, 29 Meeting of ISE, Part II, Extended Abstracts, p.830, Budapest, Hungary, 1978.

 

D. Pavlov, Z. Dinev, Dependence of the lead electrode photo-electrochemical properties on the oxidation potential in H2SO4 solution, 29 Meeting of ISE, Part I, Extended abstracts, p. 455, Budapest, Hungary, 1978.

 

D. Pavlov, T. Rogatchev, Dependence of the phase composition of the anodic layer on oxygen evolution and anodic corrosion of lead electrode in lead dioxide potential region, Electrochim. Acta, 23 (1978) 1237.

 

D. Pavlov, St. Ruevski, Thermopassivation of lead-acid battery plates, 29 Meeting of ISE, Part II, Extended Abstracts, p.836, Budapest, Hungary, 1978.

 

D. Pavlov, Processes in solid state at anodic oxidation of a lead electrode in H2SO4 solution and their dependence on the oxide structure and properties, Electrochim. Acta, 23 (1978) 845.

 

D. Pavlov, Mechanism of the processes of anodic oxidation of the lead electrode in a H2SO4 solution, III. Internationales Symposium "Elektrochemische Stromquellen", Extended Abstracts, p. 76, Technische Universitat Dresden, DDR, 1978.

1977

V. Iliev, D. Pavlov, Influence of Lead Oxide Modification on the Kinetics of Formation of Basic Lead Sulphates, 28 Meeting ISE, Electrochemical Power Sources, Extended Abstracts, p.109, Varna, Bulgaria, 1977.

 

D. Pavlov, T. Rogachev, Mechanism of Lead Anodic Oxidation in a Solution of H2SO4 at Potential from the Lead Dioxide Region, 28 Meeting ISE, Electrochemical Power Sources, Extended Abstracts, p.87, Varna, Bulgaria, 1977.

 

D. Pavlov, St. Ruevski, Processes at Thermopassivation of the Lead Dioxide Plate of the Lead-Acid Batteries, 28 Meeting ISE, Electrochemical Power Sources, Extended Abstracts, p.97, Varna, Bulgaria, 1977.

 

D. Pavlov, S. Zanova, G. Papazov, Photoelectrochemical properties of the lead electrode during anodic oxidation in sulphuric acid solution, J. Electrochem. Soc., 124 (1977) 1522.

 

D. Pavlov, S. Zanova, G. Papazov, Photoelectrochemical Properties of the Lead Electrode during Anodic Oxidation in Sulphuric Acid Solution, 28 Meeting ISE, Electrochemical Power Sources, Extended Abstracts, p. 64, Varna, Bulgaria, 1977.

 

T. Rogatchev, St. Ruevski, D. Pavlov, Mechanical and corrosion properties of low antimony lead alloys, J. Appl. Electrochem., 6 (1976) 33.

 

D. Pavlov, The elementary physicochemical processes during the first stage of formation of the negative lead-acid battery plate, J. Electroanal. Chem., 72 (1976) 319.

1976

D. Pavlov, G. Papazov, Dependence of the properties of the lead-acid battery positive plate paste on the processes occurring during its production, J. Appl. Electrochem., 6 (1976) 339.

1975

Д. Павлов, Элементарные физикохимические процессы первого периода формирования отрицательной пластины свинцового аккумулятора, Сб. Электрохимические сочники тока, р. 65, Praha Zari, Dum Techniky CVTS, Praha, CSSR, 1975.

 

Д. Павлов, Т. Рогачев, Влияние мышьяка на электрохимические процессы, которые протекают при анодной поляризации свинцовых сплавов в растворе серной кислоты, Сб. Электрохимические источники тока, р. 53, Praha Zari, Dum Techniky CVTS, Praha, CSSR, 1975.

 

Д. Павлов, Ст. Руевски, Стационарная вольтамперная характеристика свинцового электрода в сярной кислоте. Сборник Электрохимические источники тока, Praha Zari, Dum Techniki CVTS, Praha, (1975) 69.

 

Д. Павлов, Г. Папазов, Зависимост емкости положительной пластины свинцового аккумулятора от фазового состава и структуры пасты и активной массы, Сб. Электрохимические источники тока, р. 49, Praha Zari, Dum Techniky CVTS, Praha, CSSR, 1975.

 

Д. Павлов, В. Илиев, Влияние расширителя на процесс приготовления паст для отрицательных свинцовых пластин аккумуляторов, Электрохимия, 12 (1975) 1735.

 

Д. Павлов, В. Илиев, Влияние расширителя на процесс приготовления паст для отрицательных свинцовых пластин аккумуляторов, Сб. Электрохимические источники тока, р. 57, Praha Zari, Dum Techniky CVTS, Praha, CSSR, 1975.

1974

D. Pavlov, V. Iliev, G. Papazov, E. Bashtavelova, Formation processes of the lead-acid battery negative plate, J. Electrochem. Soc., 121 (1974) 854.

1972

D. Pavlov, Mechanism of the processes of formation of lead-acid batteries positive and negative plates, Proceedings of Symposium on Batteries for Traction and Propulsion, Columbus Section of the Electrochemical Society, p. 135, USA, 1972.

 

D. Pavlov, G. Papazov, V. Iliev, Mechanism of the processes of formation of lead-acid batteries positive plates, J. Electrochem. Soc., 119 (1972) 8.

 

A. Kirov, T. Rogatschev, D. Denew, Metalloberflache, 26 (1972) 234

1970

T. Rogatchev, W. Karoleva, D. Pavlov, Einfluss der legierenden Zusatze aus Silber und Thalium auf die Geschwindigkeit der anodischen Korrosion und die mechanischen eigenschaften des Bleis in Schwefelsaure, Metalloberflache, 24 (1970) 421.

 

D. Pavlov, R. Popova, Mechanism of passivation processes of the lead sulphate electrode, Electrochim. Acta, 15 (1970) 1483.

 

D. Pavlov, N. Iordanov, Growth processes of the anodic crystalline layer on potentiostatic oxidation of lead in sulphuric acid, J.Electrochem. Soc., 117 (1970) 1103.

1969

D. Pavlov, C.N. Poulieff, E. Klaja, N. Iordanov, Dependence of the composition of anodic layer on the oxidation potential of lead in sulphuric acid, J. Electrochem. Soc., 116 (1969) 316.

1968

D. Pavlov, T. Rogatchev, Einfluss von Silber und Thallium auf die anodische Korrosion der Bleilegierungen in Schwefelsaure, Werkstoff und Korrosion, 19 (1968) 677.

 

D. Pavlov, Processes of formation of divalent lead oxide compounds on anodic oxidation of lead in sulphuric acid, Electrochim. Acta, 13 (1968) 2051.

1967

D. Pavlov, Mechanism of the anodic oxidation of lead in sulphuric acid solution, Berichte der Bunsen-geselschaft, 71 (1967) 398.

1965

Д. Павлов, М. Ботон, М. Стоянова, Анодна корозия на олово-антимонови сплави с добавки на сребро, Изв. ИФХ, 5 (1965) 55.

 

J. Belloni, D. Pavlov, Adsorption ionique positive et negative en solution aqueuse diluee sur divers oxydes et hydroxydes metalliques, J. Chimie Physique, 48 (1965) 458.

1962

St.G. Christov, N. Pangarov, D. Pavlov, Wasserstoffuberspannung am kubischen Cobalt, Dokl. BAN, 15, 5 (1962) 511

 

D. Pavlov, J. Belloni, Repulsion d'ions en solution aqueuse diluee par des oxydes et hydroxydes metalliques, Comptes rendu, ASF, 255 (1962) 2420.

1959

К. Първанов, Св. Райчева, Д. Павлов, Повышение износоустойчивости контактных медных покритий, Полярографское производство СССР, 4 (1959) 14.

1958

Д. Павлов, Н. Еленкова, Върху адсорбцията на арсеноводорода от калиев йодат и използването и за полярографското определяне на арсена, Известия на Химическия Институт на БАН, 6 (1958) 33.

 

Д. Павлов, Д. Лазаров, Полярографское исследование комплексов трехвалентной сурьмы в растворах фтористого натрия, Докл. АН СССР, 118, 1 (1958) 103.

 

Д. Павлов, Д. Лазаров, Полярографское исследование комплексных соединений трехвалентной сурьмы в растворах фтористого натрия, Ж.Н.Х. АН СССР, 3 (1958) 2099.

 

Д. Лазаров, Д. Павлов, Използване на антимонофлуоридния комплекс в аналитичната практика, Химия и индустрия, 30 (1958) 166.

1955

А. Трифонов, Ч. Иванов, Д. Павлов, Полярографски метод за определяне на сяра в органични съединения, Известия на Химическия Институт на БАН, 3 (1955) 3.

1954

A. Trifonoff, Tsch. Ivanov, D. Pavlov, Polarographische Methode der Schwefelbestimmung in organischen Verbindungen, Collection Czechoslov.Chem.Commun., 19 (1954) 1133.

 

A. Trifonoff, Tsch. Ivanov, D. Pavlov, Polarographische Bestimmung des Schwefels in organischen Verbindungen, Dokl. BAN, 7 (1954) 1.